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Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I)
Beschreibung
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
- Coupling reactions
- Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides
- Especially active in difficult aminations
Spezifikation
Spezifikation
| Color | Green |
| Linear Formula | [Pd(C4H9)3PBr]2 |
| Quantity | 0.1 g |
| Sensitivity | Air sensitive |
| Solubility Information | Soluble in benzene and tolueneSoluble in tetrahydrofuran,toluene,dichloromethane and chloroform; Insoluble in alcohols and water. |
| Formula Weight | 777.29 |
| Physical Form | Powder |
| Chemical Name or Material | Di-mu-bromobis (tri-tert-butylphosphine)dipalladium (I) |
Sicherheit und Handhabung
- Di-my-bromobis(tri-tert-butylphosphine)dipalladium(I)
- Warning
- Serious eye damage/eye irritation Category 2
- Skin corrosion/irritation Category 2
- Specific target organ toxicity Category 3
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
- H335-May cause respiratory irritation.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P312-Call a POISON CENTER/doctor/if you feel unwell.
- P332+P313-If skin irritation occurs: Get medical advice/attention.
- P337+P313-If eye irritation persists: Get medical advice/attention.
- MIXTURE LIST-Contain: Di-my-bromobis(tri-tert-butylphosphine)dipalladium(I)
RUO – Research Use Only
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