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  6. Thermo Scientific Chemicals Réactif Burgess, 96 %

Thermo Scientific Chemicals Réactif Burgess, 96 %

Product Code. 11328966
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Product Code. 11328966 Supplier Thermo Scientific Chemicals Supplier No. L20155.03
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Description

CAS: 29684-56-8 | C8H18N2O4S | 238.30 g/mol

Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Le réactif de Burgess est un réactif déshydratant sélectif utilisé dans la synthèse organique. Il est utilisé pour convertir l’alcool secondaire et tertiaire, avec un proton adjacent, en alcènes. Le réactif de Burgess est également utilisé pour promouvoir de grandes valeurs synthétiques en chimie médicale. Il a été utilisé dans la déshydratation des amides primaires, des formamides et des nitroalcanes primaires pour générer respectivement des nitriles, des isocyanures et des oxydes de nitrile. Il forme des uréthanes lorsqu’il réagit avec les alcools primaires.

Solubilité
Soluble dans les solvants organiques.

Remarques
Stockez-le dans un endroit frais. Sensible à l’humidité. Incompatible avec les agents oxydants forts.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 29684-56-8
Formule moléculaire C8H18N2O4S
Poids moléculaire (g/mol) 238.30
Numéro MDL MFCD00077815
Clé InChI YSHOWEKUVWPFNR-UHFFFAOYSA-N
Synonyme methoxycarbonylsulfamoyl triethylammonium hydroxide, burgess reagent, carbomethoxysulfamoyltriethylammonium hydroxide, methoxycarbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulphamoyltriethylammonium hydroxide, methoxy-carbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulfa-moyl-triethylammonium hydroxide, methoxycarbonylsulphamoyl-triethylammonium hydroxide
CID PubChem 11032497
SMILES CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC

Specifications

Nom chimique ou matériau Burgess Reagent
Point de fusion 72°C to 82°C
Quantité 1 g
Beilstein 1432131
Sensibilité Moisture sensitive
Informations sur la solubilité Soluble in organic solvents.
Nom IUPAC triéthyl({[(méthoxycarbonyl)imino](oxido)oxo-λ⁶-sulfanyl})azanium
Poids de la formule 238.3
Pourcentage de pureté 96%

RUO – Research Use Only

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