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  8. Diacétate d’iodosobenzène, +98 %, Thermo Scientific Chemicals

Diacétate d’iodosobenzène, +98 %, Thermo Scientific Chemicals

Product Code. 11430368
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Product Code. 11430368 Supplier Thermo Scientific Alfa Aesar Supplier No. B24531.36
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Description

CAS: 3240-34-4 | C10H11IO4 | 322.098 g/mol

Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
L’iodosobenzène est utilisé comme agent oxydant et acétoxylant dans la synthèse organique. Il participe activement à la préparation de (Z)-3,7-diméthyle-2,6-octadiène-1-al(neral) à partir de (Z)-3,7-diméthyle-2,6-octadiène-1 ol (nerol) en présence de 2,2,6,6-tétraméthylpipéridine-1-oxyl (TEMPO). Il s’agit d’un réactif utile pour la synthèse d’une grande variété de composés hétérocycliques. Il est également utilisé dans la 2-arylation catalysée par Pd des indoles.

Solubilité
Insoluble dans l’eau.

Remarques
Sensible à la lumière. Incompatible avec les agents oxydants forts.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 3240-34-4
Formule moléculaire C10H11IO4
Poids moléculaire (g/mol) 322.098
Numéro MDL MFCD00008692
Clé InChI ZBIKORITPGTTGI-UHFFFAOYSA-N
Synonyme iodobenzene diacetate, diacetoxyiodo benzene, iodosobenzene diacetate, phenyliodine diacetate, phenyliodo diacetate, phenyliodoso acetate, phenyliodosodiacetate, phenyliodoso diacetate, bis acetato phenyliodine, benzene, diacetoxyiodo
CID PubChem 76724
Nom IUPAC Acétate d’[acétyloxy(phényl)-$l^{3}-iodanyl]
SMILES CC(=O)OI(C1=CC=CC=C1)OC(=O)C

Specifications

Nom chimique ou matériau Iodosobenzene diacetate
Point de fusion 159°C to 161°C
Quantité 500 g
Beilstein 1879369
Sensibilité Light sensitive
Informations sur la solubilité Insoluble in water.
Poids de la formule 322.1
Pourcentage de pureté ≥98%

RUO – Research Use Only

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